Two isomorphous Mn(II) and Co(II) 5-amino-tetrazolate coordination polymers with magnetic Δ-chains: crystal structures and magnetic properties.
نویسندگان
چکیده
Two Co(II) and Mn(II) coordination polymers, which have been synthesized under hydrothermal conditions, are isomorphous with magnetic Δ-chains containing trinuclear triangular [M(3)(μ(3)-OH)] clusters. The Δ-chains are bridged by isonicotinic spacers to generate a two-dimensional scalariform layer structure. Magnetic investigations indicate that Co(II) compound exhibits not only spin canting but also metamagnetic behaviors, while only spin-canted antiferromagnetic behaviors was observed in Mn(II) compound.
منابع مشابه
Isomorphous tetrazolate MnII and CoII compounds built on Δ-chain showing different magnetic behaviors.
As a continuation of the study on using the tetrazolate ligands to construct coordination polymers, two isomorphous 3D coordination polymers built on Δ-chain topological rod-shaped SBUs have been synthesized with formulae [M(2)(μ(3)-OH)L(1)L(2)](n) (5-amino-1H-tetrazole (HL(1)), 2,3-pyrazinedicarboxylic acid (H(2)L(2)) and different 3d spin carriers (M = Mn(II), 1 and Co(II), 2)). The SBU consi...
متن کاملNovel manganese(II) and cobalt(II) 3D polymers with mixed cyanate and carboxylate bridges: crystal structure and magnetic properties.
Two isomorphous 3D Mn(II) and Co(II) coordination polymers with a dicarboxylate inner salt and cyanate as coligands were synthesized and structurally characterized, and their magnetic properties have been studied. In the compounds, [M(L)(NCO)](n).nH(2)O (M = Mn, Co, L = 1-carboxymethylpyridinium-4-carboxylate), neighboring metal ions are linked by the 3-fold bridges of an end-on cyanate and two...
متن کاملSynthesis and characterisation of Mn(II), Co(II) and Cd(II) coordination polymers of 1,2,4-triazole-3, 5-dicarboxylic acid.
Three new coordination polymers ([Mn(3)(dctrz)(2)(H(2)O)(8)](n) (1), [Co(Hdctrz)(H(2)O)(3)](n) (2) and [Cd(Hdctrz)(H(2)O)(2)](n) (3), H(3)dctrz, 1-H-1,2,4-triazole-3,5-dicarboxylic acid) based on the self-assembly of Mn(2+), Co(2+) and Cd(2+) ions with H(3)dctrz have been synthesized and characterized by single crystal X-ray diffraction analysis. Variable temperature magnetic studies are invest...
متن کاملThree-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: synthesis, structure and magnetic properties.
Two 3D coordination polymers of Mn(II) with azide and bifunctional zwitterionic ligands bearing both carboxylate and tetrazolate groups, 1-(carboxylatomethyl)-3-(5-tetrazolato)pyridinium (L(1)) and 1-(carboxylatoethyl)-4-(5-tetrazolato)pyridinium (L(2)), were synthesized, and structurally and magnetically characterized. They are formulated as [Mn(3)(L(1))(2)(N(3))(4)(H(2)O)(2)](n)·4nH(2)O (1) a...
متن کاملUtilization of a ligand containing 2,2'-bipyridyl and tetrazolate groups to construct a 2D Co(II) coordination polymer: spin canting and metamagnetism.
The use of anions of 6,6'-bis(1H-tetrazol-5-yl)-2,2'-bipyridine (H2btzbp) as chelating ligands in preparing a coordination polymer is described. The synthesis, X-ray crystal structure and magnetic properties of a new Co(II) coordination polymer, [Co(btzbp)]n (1), are reported. The in situ [2 + 3] cycloaddition reaction of 6,6'-dicyano-2,2'-bipyridine with sodium azide in the presence of Co(ClO4...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 41 17 شماره
صفحات -
تاریخ انتشار 2012